Sulfur compounds and wine have a long common history:

Invented about 8,000 years ago, several centuries before the invention of the wheel, wine is one of the world's oldest beverages, after beer and water. Ancient mythology is full of this symbol, with revered gods such as Dionysus for the Greeks and Bacchus for the Romans. The use of sulfur compounds in wine production is equally ancient.

According to some legends, the Romans added sulfur extracted from the Etna volcano directly to wine to help preserve it. Although these legends are probably true, it was only at the end of the 15th century that a German royal edict was found. The latter allows the addition of sulfur compounds. The presence of sulfites in wine was not revealed until 10 years ago, but mandatory labeling on bottles appeared.

Sulfites, a natural and indispensable element in winemaking:

Sulfur dioxide (SO2) is involved in various stages of the winemaking process. Its antiseptic properties prevent the emergence of harmful microorganisms such as bacteria. Therefore, its presence in bottles prevents the wine from going through a second fermentation or even producing vinegar. Sulfur dioxide is also an antioxidant. This is why it prevents the wine from tasting like cider. Yeasts intended to produce alcohol naturally produce sulfur dioxide and are therefore found in all living things.

Sulfur dioxide is mostly used in the final bottling stage. European standards have set maximum sulfur dioxide levels to be used in wine. Red wine should not exceed 160 mg/L sulfite and white wine should not exceed 210 mg/L. Secondly, since transportation and storage are more delicate, they may contain more sulfites.

Do sulfites cause headaches?

The presence of the phrase “contains sulfites” on bottle labels has been the source of much controversy. The parallel between sulfites in wine and headaches is based on the origin of the sulfur used.

Anthropogenic sulfur, unlike natural sulfur, is never completely pure (burning fossil fuels). For this reason, many independent winemakers are starting to limit the use of sulfur, and when they do use it, they are choosing natural sulfur.

Many people believe that sulfites are responsible for the “harsh result.” Paradoxically, sulfur is found in dried fruits, egg yolks and many vegetables, and excess of these does not cause post-morning headaches. These are mainly caused by thirst caused by alcohol and not by sulfites, the presence of which is regulated and limited.

For the amount of sulfur in wine to become truly harmful to human health, you would have to drink very large amounts every day. So remember to drink small amounts to avoid sulfur poisoning!

Find our full range of gas detection and respiratory protection equipment for winegrowers, especially for the prevention of CO2 risks in winemaking.

Every year during the harvest period, people suffer from CO2 poisoning…

Carbon dioxide in winemaking

CO2 Carbon dioxide (also known as carbonic gas or carbon anhydride) is a dangerous, odorless and colorless gas that is heavier than air. In the winegrowing industry, the CO2 hazard is mainly in barrels. and when working in buildings (cellars), it occurs especially at the lower points of the facilities because CO2 is heavier than air, so it sits on the ground…

During the fermentation process, one liter of wine produces 44 liters of CO2 . This gas comes mainly from the alcoholic fermentation of the wort. The process begins when the grape skin cracks and the temperature exceeds 12°C. Sugar also encounters yeasts present on grape skins or in the air and gradually turns into alcohol.

During the fermentation process, it gives the wine its softness carbon dioxide , ethanol (alcohol) and secondary compounds such as glycerols, succinic acid, acetic acid, which is a vinegar acid, and aromatic compounds (esters) from banana or raspberry found in young wines (Beaujolais nouveau) are emitted.

Check out our selection of gas detector equipment for wineries and breweries.

CO2 risks and dangers:

Over time and experience, dangers become habitual for permanent employees, so attention decreases... For temporary employees, the danger is ignorance of the fermentation process and lack of knowledge... CO2 dangers in numbers:

  • 400 ppm is the CO2 content in clean (and healthy) air
  • 1000 ppm (0.1%): Indoor comfort limit
  • 2000 ppm (0.2%): Increased respiratory rate
  • 5000 ppm (0.5%): Hygiene maximum value (laboratory control)
  • 10,000 ppm (1%): Increased heart and respiratory rate
  • 30,000 ppm (3%): Respiratory problems
  • 80,000 ppm (8%): ​​Cramps and fainting within minutes
  • 200,000 ppm (20%): Loss of consciousness and death within a few seconds

How to protect yourself from CO2 poisoning?

  • Provide effective ventilation with fresh, clean air in wine production facilities.
  • Perform permanent CO2 monitoring with a fixed gas detection system such as the GLACIÄR MIDI detector or, if this is not possible, use a portable CO2 detector
  • Equipped with rapid and effective intervention tools: self-contained breathing apparatus for rescue or evacuation, seat belt…
  • Watch out for accidents... During the rescue in tanks, 1 out of every 3 injured people turned out to be drunk!

Composition and use of biogas

methanization , that is, organic substances (vegetable or animal substances) decomposition ) or anaerobic digestion of domestic waste, It produces a gas called biogas. This, methane (CH4) (usually between 50% and 70%) carbondIoxide , at a low rate hydrogen sulfide (responsible for the odor of this gas) and in varying concentrations of water vapor is a mixture. Biogas, especially in swamps and in the wastelands in the atmosphere naturally can be produced. Also, especially wastewater and sludge treatment in the digesters during artificially is synthesized. in the food industry is also available.

Shares of biogas

Institutions, according to international climate scientists, the global climate change in recent years has been focusing on biogas for several years, as it is a part of In France, since the publication of the decree dated 9 September 1997, recycling biogas in waste land It is mandatory. Biogas recycling is of ecological interest as it could be an alternative to fossil fuel power. Therefore, economic activity linked to biogas is being developed: in 2012 there were 214 production facilities, while at the end of 2013 this number was 848. If it is not recycled, it must be incinerated. The main reasons for recycling or disposal are its toxicity, explosiveness and large volume.

Properties of biogas and its effects on health

Biogas is a flammable gas because it consists mostly of methane, but hydrogen sulfide and caustic because it contains a gas toxic is a gas. The digestive process involves the movement of bacteria and particles, which can lead to a variety of effects in humans. Therefore, an optical flame detector such as the Spyglass SG50 is ideal for detecting methane, avoiding the risks of methane, especially thanks to the color video option.

in the eyes (conjunctivitis) and nasal (cold) irritations and nausea are symptoms of high levels of exposure over a short period of time. Chronic exposure does not cause death, but rather effects the brain (headaches and chronic fatigue) or the digestive system (abdominal aches and nausea). organ failure leads to . Risks to humans are quite minimal if all basic precautions associated with activity around this gas are taken.

Precautions and protection tools against biogas

  • Since biogas is explosive, a 4-gas detector, such as the X-am 2500 portable gas detector, enables monitoring of biogas concentrations
  • To obtain an accurate analysis of changes in biogas concentrations, the use of specialized equipment such as the Biogas 5000, a biogas analyzer, should be preferred over conventional gas detectors (fixed or portable) that may not be able to monitor such significant concentrations.
  • Because biogas contains very high concentrations of H2S (sometimes up to 10,000 ppm) and asphyxiating gases (such as CH4 or CO2), a protective air-purifying mask is not suitable and an atmosphere that provides respiratory protective equipment (a self-contained breathing apparatus or airway system) is required. will be heard.

The development of the refrigeration industry, especially with refrigerants, has made it possible to transport food thousands of kilometers from its production sites. The European Union is the second largest market for deep frozen products.

Use of ethylene as a refrigerant

The chemical properties of some gases, such as boiling temperature, affect food products. It offers numerous opportunities for storing and transporting over longer distances. . Many refrigerants used in the past have been abandoned due to their harmful effects on global warming.

Refrigeration industries now have low or no impact on climate is turning to natural gases. Ethylene (C2H4) is part of these gases. Although thousands of tons are produced from human sources every year, Almost 74% of emissions come from natural sources.

Since the boiling point of ethylene is -103 °C, this gas a very low temperature refrigerant It is considered . Therefore, its use is limited to some foods. Many companies use ethylene mixed with water to synthesize ethylene glycol. This cooling medium is adapted to low temperature protection.

Use of ethylene in fruit ripening

To ripen climate fruits like kiwis or bananas. produces ethylene . To be edible in a remote country, coolants are not enough.

In addition to coolers, a ventilation system is often installed in warehouses to prevent ethylene accumulation due to fruit ripening. This process is used to slow down the growth and ripening of fruits. Thus, food can be transported without the potential risk of major losses caused by over-ripening.

Once the food reaches the consumer country, it is stored in warehouses that emit low ethylene concentrations. These concentrations are too low to be toxic and is calculated to be exactly equal to the amount that the climacteric fruit will produce to ripen.

Various research projects on the number of deaths caused by atmospheric pollution observe that 3.3 to 8.8 million people in the world, mostly in Asia, will die prematurely due to symptoms related to ozone and fine particle pollution.

Ozone atmospheric pollution

This pollution should not be confused with the ozone layer located at very high altitudes. Bad ozone It is located at low altitude. such as carbon oxides (NOx) or hydrocarbons It is the result of various compounds. The main source of this pollution is cars. At high temperatures or lack of wind Since ozone remains in the atmosphere is more important.

Symptoms are versatile depending on duration and frequency of exposure as well as concentrations. They range from mild irritation of the eyes and respiratory tract (tingling in the eyes and nose) to respiratory illnesses.

Fine particles atmospheric pollution

Diameter less than 2.5 micrometers Particles that are are considered fine. These particles give shape and consistency to smokes. The main emissions come from cars, but also from forest fires and heating appliances.

These infinitely small particles pass directly through the respiratory tract unhindered and settle in the lungs. They are responsible for respiratory diseases and infections resulting from repeated and prolonged exposures over the long term.

Atmospheric pollution from nitrogen compounds

Nitrogen such as nitrogen dioxide (NO2) and nitric oxide (NO) compounds It is mainly expelled by the internal combustion engine (diesel), but also by thermal power plants or raw material combustion. Therefore, urban areas are primarily affected by this pollution.

However, nitrogen oxides are very toxic and are widely used as fertilizers in the food industry. Therefore, there is a risk when fertilizers are spread on fields, especially in rural areas

What is a colorimetric gas detector tube

It is a closed tube made of glass that contains a chemical substance to monitor and react (with a color change) in the presence of the target gas or vapor. Gratuations, usually in ppm (parts per million) or %/vol (percentage of volume), offer very accurate measurements with relative immunity to interfering substances.

Application area of ​​gas detector tubes

Due to the large number of gases in the atmosphere or formed as a result of chemical reactions, it is not possible to detect all of them with a gas detector.

Having a surprising range of gases (hundreds) colorimetric gas detector tube It can be a particularly suitable and relevant solution in many cases. As well as being as easy to use as an alcohol analyzer, they are also affordable – a few dozen euros for a pack of 10 tubes.

Different categories of gas detector tubes:

There are two categories of gas detector tubes: colorimetric tubes and dosimeter tubes (also known as dosi tubes). Colorimetric plates also exist, but they are much less common and more complex to use.

  • Colorimetric tubes:

These units are by far the best known and most used due to the large number of toxic or asphyxiating gases they can monitor. To date, approximately 500 references are available for use in various fields of activity. Colorimetric gas detector tubes are instant measurement systems and must be used with a sampling pump. Gastec reagent tubes use special pumps to precisely sample a specific volume of gas. Colorimetric reagent tube is one-time gas concentrations where the result can be obtained within seconds. Dräger colorimetric reagent tubes are renowned for their efficiency and instant measurement.

  • Dosimetric tubes:

This is a TWA (Time Weighted Average) measurement system that measures gas concentration over a fixed period of time (e.g. 8 hours represents a working day). There is no need for a pump for this type of gas detector tubes, the gas concentration is read directly in the tube after exposure. This is an ideal and cost-effective solution for measuring gas exposure in working environments: exhaust gases, formaldehyde, paint shops…

Regardless of the fumes generated during welding, they have been classified as carcinogenic substances by IARC (International Agency for Research on Cancer) since 1990.

Dangerousness of welding fumes

The metal being welded is never completely cleaned, the fumes produced during welding are dangerous and stored. The presence of oils, dyes or some thin oils produces highly carcinogenic products such as formalin or polycyclic aromatic hydrocarbons (or polyaromatic hydrocarbons).

These fumes appear in two stages. First, the weather. decomposition (emission of CO, CO2, ozone, nitrogen vapors, etc.) is the resulting gas phase . Secondly, it is made of welded metals. respirable fumes and dust but also caused by the electrode in the form of aluminum or chrome is the particle phase.

Protection against welding fumes

To protect against these carcinogenic factors, there are three different respiratory protection methods depending on the nature of the welding activity:

Source gas masks : Lightweight and ergonomic, highly effective filtering respiratory protection for occasional or short-term work They offer . They are positive pressure devices, meaning the user exerts respiratory effort.

Powered air-supported breathing apparatus for welders : With positive pressure systems that inject breathable air into the headgear They are ideal for long-term work . However, the use of these units requires an oxygen concentration rate higher than 19.5%.

Stand-alone devices for welders : used primarily for working in closed spaces (sinks, holes, pits, crawl spaces, pipes, tanks, sewers…) where the atmosphere is unbreathable (when the oxygen concentration rate is below 19.5%). They are divided into two categories: self-contained breathing apparatus And airway devices . The first category is ideal for short-term jobs, and the second category is ideal for long-term or tiring jobs.

What is a volatile organic compound?

Volatile organic compounds, better known as VOCs, thousands of items (such as hydrocarbons, solvents, preservatives, alcohols…) and biogenic , that is, natural or anthropogenic It may be (man-made). Due to their incredible numbers, volatile organic compounds (VOCs) can be found in almost every field of activity (medical, food industry, refineries…) and even in the home (paints, varnishes, cosmetics…). Because they are volatile, they spread around the emission source and are dangerous. Although some VOCs have a low impact on health (visual and odor nuisance), others are highly toxic and even carcinogenic.

The same happens when dissolved in water formalin or formic aldehyde This also applies to formaldehyde, also known as formaldehyde.

This volatile organic compound belongs to the aldehyde family, formed as a result of the chemical transformation of an alcohol or incomplete combustion of fuel or wood. This article It is very harmful to humans and many in the field of activity (industry, agriculture, photography), in houses (foam pressed boards used for insulation, concrete, plaster, woodworking…) and even in tobacco smoke can be found .

Dangers of formaldehyde exposure:

For brief introduction:

At ambient temperature, formaldehyde (or methanal) is extremely flammable and depending on its properties, it may form explosive mixtures in air. Brief exposure (more than 0.1 ppm for 15 minutes) may cause skin irritation, especially eczema, burning sensation in the eyes, and breathing difficulties. loss of sensation causes . Even at low doses, formaldehyde causes severe ulceration of the digestive tract, although cases of ingestion are rare.

For long-term exposure:

Long-term exposure to formaldehyde leads to rapid deterioration of respiratory capacities: nasal lesions, cough, asthma, pulmonary system failure. The World Health Organization's International Agency for Research on Cancer (IARC) recommends formaldehyde category 1 carcinogenic substance classified as , which means that its carcinogenic effects in humans have been proven. Indeed, results of epidemiological studies reveal a clear causal relationship between formaldehyde exposure and nasopharyngeal cancers. However, the results do not guarantee a definitive link between this volatile organic compound and leukemia.

How to protect against formaldehyde:

Before protecting against formaldehyde, it must be detected. The simplest and most economical solution is to use colorimetric reagent tubes such as Dräger tubes with gas point measurement. Reagent tubes (with pumps, such as Gastec tubes) provide instantaneous measurement of gas concentration, while dosimetric tubes measure average exposure to the gas. A VOC detector would be useful for more in-depth study and functionality.

 

The simplest and most cost-effective solution is the gas detector tube system. Actually colorimetric gas detection tubes ( Gastec reagent tubes (such as pumped ones) allow instantaneous measurement of a time-weighted average of exposure to this gas. A volatile organic compound detector will be useful for precise monitoring and more complete functions.

Once detected, air-purifying respiratory protective equipment makes it possible to protect against it. With type B filter cartridge half masks or full face gas masks It offers the best protection against this volatile organic compound. A full respirator that protects the eyes should be preferred to prevent any eye irritation.

What is phosphine?

Phosphine (PH3) is a gas composed of phosphorus hydride (its official and international name is phosphane). PH3 is a colorless, flammable and very toxic gas with a fishy or garlic odor. Phosphine acts on the central nervous system and lungs, causing pulmonary edema. Symptoms such as weakness, vomiting, headache, and chest tightness may occur rapidly after exposure. Exposure to high concentrations of phosphine – even short-term – can lead to chronic neurological problems, so people who work with or are around phosphine should be extremely careful. Therefore, industries working with this toxic substance must have a detector to avoid risks, such as the SI-H100 gas detector with integrated sampling pump.

What is phosphine gas fumigation?

Fumigation is a technical process that consists in spraying a gas in a closed cabinet (barrel, skid, crate, container) to destroy pests (mostly living organisms (bugs, beetles, moth, rodents…)); The most commonly used gas is phosphine.

This method is mandatory for international shipping, for example, to prevent bacteriological contaminations or the introduction of animals or insects from one continent to another. The only gases authorized by FAO are hydrogen phosphide or phosphine (PH3) and methyl bromide (CH3 Br).

What are the dangers of PH3 exposure?

Phosphine is very dangerous for humans. For example, in 2010, two dock workers in the Netherlands were seriously poisoned while unloading a container from China containing a high concentration of toxic gas, and one of them was in a coma for 5 days.

How to detect phosphine gas and how to protect it?

Persons who may be in contact with PH3, such as warehouse workers or customs officers, should be systematically equipped with a PH3 phosphine gas detector as personal protective equipment. Additionally, people working in confined spaces potentially contaminated with phosphine or working with this gas are strongly recommended to wear a gas mask with a type B cartridge adapted for phosphine filtration.

In conclusion, phosphine gas fumigation is a delicate process that is often necessary for workers but involves real dangers and must be carried out with extreme caution!

Sarin (GB) It is odorless, colorless and volatile (liquefies at ambient temperature) and belongs to the family of organophosphates. It is extremely toxic to humans and animals. It is estimated that this gas is 500 times more toxic than cyanide.

This is neurotoxic – soman (GD) , tabun (GA) And VX (10 times more lethal than sarin) – it is extremely dangerous (0.01 ppm of this gas can be lethal) enters the respiratory tract or simply through skin contact (but can also be used to poison water or food) and mixes directly with the blood and affects the nervous system. It prevents the transmission of sensory impulses and causes death due to cardiorespiratory arrest. The injured first feel severe headaches and their pupils dilate. They then convulse, experience respiratory arrest before falling into a coma and dying.

sarin gas, By the United Nations on 3 April 1991 (resolution 687) « weapon of mass destruction » before being classified as a chemical war It is considered . Therefore, its production and preservation has been prohibited since 1993.

How to protect yourself from sarin gas (sarin gas mask)?

gas mask Remember that (or rather anti-gas mask) only protects the respiratory tract . As mentioned above, sarin gas can also be absorbed through the skin –NBC le gas sarin can also be peau (NBD protection equipment required) or swallowed…

For respiratory protection against sarin gas covering a wide range of hazards Type ABEK2-P3 (also coded A2B2E2K2-P3) We recommend panoramic gas masks with filtering cartridges:

Each filter cartridge is characterized by a set of letters (type of protection: ABEKP) and numbers (absorption class: 1-2-3):
A : Organic gas and vapor (solvents) with a boiling point above 65°C
B : Inorganic gas and vapor (chlorine, hydrogen sulfide, sulfure d'hydrogène, hydrogen cyanide).
E : Acid gas and vapor such as sulfur dioxide.
K : Ammonia and organic compounds
P : Solid and liquid particles, Particules solides et liquides, radioactive and highly toxic particles, bacteria and viruses

Our « How to choose a filtration cartridge » tool available on the GTC Industrial website allows you to determine the type of cartridge you need based on the gas(es) encountered, with a description of each cartridge available…

Even more «protective», like Scott Safety’s TORNADO, made of hypalon (high resistance to chemical products) that covers the entire head and shoulders. has an integrated hood (used with NBC protection equipment) and With A2B2E2K2Hg-PSL filter cartridge a powered air-assisted respirator

Powered air-supported respirator TORNADO consists of 3 units: ventilation system (« engine »), filter cartridge(s) and facepiece (hood, mask…). The engine sucks ambient air through filters and injects it into the head protection through a corrugated hose.

Assisted ventilation reduces respiratory effort and fatigue resulting from the use of filtered respiratory protection equipment. This is a respiratory protection system especially adapted for long-term work or high temperature situations. Assisted ventilation Overpressure in the head ensures a high nominal protection factor.

All types of filtered respiratory protection devices (gas masks, powered air-assisted respirators…) It definitely requires at least 17% oxygen volume, otherwise it will be necessary to use a self-contained breathing apparatus…